孙立成

个人信息Personal Information

教授

博士生导师

硕士生导师

主要任职:无

其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工

办公地点:大连理工大学西部校区化工实验楼E-223

联系方式:0411-84986493

电子邮箱:sunlc@dlut.edu.cn

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Assembling Supramolecular Dye-Sensitized Photoelectrochemical Cells for Water Splitting

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论文类型:期刊论文

发表时间:2015-12-07

发表刊物:CHEMSUSCHEM

收录刊物:SCIE、EI、PubMed、Scopus

卷号:8

期号:23

页面范围:3992-3995

ISSN号:1864-5631

关键字:electrochemistry; molecular devices; photochemistry; water oxidation; water splitting

摘要:The method used to assemble dye-sensitized photoelectrochemical (DS-PEC) devices plays a vital role in determining its photoactivity and stability. We report a simple and effective method to assemble supramolecular DS-PECs introducing PMMA as support material and a catalyst modified with long carbon chains as photoanodes. The long carbon chains in combination with PMMA allow to better immobilize the catalyst. DS-PECs obtained by this simple method have display excellent photoactivities and stabilities. A photocurrent density of 1.1mAcm(-2) and a maximum IPCE of 9.5% have been obtained with a 0.2V vs NHE external bias.