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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Catalytic effect of cobalt and iron complexes incorporating bis(2-aldiminoethyl)amine ligands on ethylene oligomerization
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论文类型：期刊论文
发表时间：2003-04-01
发表刊物：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
收录刊物：SCIE、CSCD
卷号：19
期号：2
页面范围：231-234
ISSN号：1005-9040
关键字：cobalt and iron complexes; Schiff base; bis(2-aldiminoethyl)amine; ethylene oligomerization; low carbon olefin
摘要：Complexes [MCl2 {CH3N (CH2CH2N = (CRR)-R-1)(2))}](3, M = Co, R-1 = H, R-1 = Ph; 4, M = Fe. R-1 = H, R-2 = Ph; 5, M = Co, R-1 = R-2 = Ph) were prepared and characterized by IR spectra and elemental analysis. The combination of each of complexes 3-5 with ethylaluminoxane (EAO), respectively, was found to be moderatety active for ethylene oligornerization to low carbon olefins. The activity of 113 kg oligomers . mol(-1) Co . h(-1) for complex 3(100 mol of EAO, 180 degreesC and 1.8 MPa ethylene) was observed with a selectivity of 93% to C4-10 olefins, of which 96% were linear C4-10 olefins. The catalytic properties of complexes 3-5 were compared with those of analogous P,P-coordinated complexes [MCl2{CH3N(CH2CH2PPh2)(2)}](1, M = Co; 2, M = Fe).