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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
Across the Board: Licheng Sun on the Mechanism of O-O Bond Formation in Photosystem II
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论文类型：期刊论文
发表时间：2019-07-19
发表刊物：CHEMSUSCHEM
收录刊物：SCIE、EI
卷号：12
期号：14
页面范围：3401-3404
ISSN号：1864-5631
关键字：disproportionation; oxygen evolution; photosystem II; structural rearrangement; water splitting
摘要：In this series of articles, the board members of ChemSusChem discuss recent research articles that they consider of exceptional quality and importance for sustainability. This entry features Prof. L. Sun, who proposes a special mechanism for O-O bond formation in photosystem II with involvement of an Mn-VII-oxo species induced by charge- and structural rearrangements. In this viewpoint, Proton transfer is involved in changes of the first coordination spheres around the Mn-VII-oxo site on the dangling Mn4 with de- and re-coordination of carboxylates (Glu333 and Asp170).
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